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1.
Mar Pollut Bull ; 198: 115930, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-38101059

RESUMO

This study assessed pollution levels, ecological and health risk, and spatial distribution of eight heavy metals in sediments of Big Giftun and Abu Minqar Islands, Red Sea, Egypt. Iron (Fe) and manganese (Mn) had the highest contents in both island sediments, while cobalt (Co) in Big Giftun and cadmium (Cd) in Abu Mingar had the lowest values. The obtained PCA data exhibited positively significant loadings of Cd, Co, copper (Cu), nickel (Ni), and zinc (Zn) with 51.03 % of data variance in Big Giftun, and lead (Pb), Cu, Mn, Ni, Zn, and Fe (37.7 %) in Abu Minqar sediments. The contamination factor (CF) showed low contamination for all metals, except cadmium; Cd (moderate). The geo-accumulation index (Igeo) values showed uncontaminated (Cd, Co), moderately (Cu), extremely contaminated (Fe, Mn) (Igeo > 5) in Big Giftun, and uncontaminated (Cd), moderately to strongly contaminated (Cu, Ni), and extremely contaminated (Fe, Mn, and Zn) in Abu Minqar sediments. The pollution load index (PLI) values indicated baseline level of contamination (PLI <1), and degree of contamination (DC) indicated low degree of contamination (DC < n) in all sediments. Nemerow pollution index (NPI) showed unpolluted sediments in Abu Minqar (NPI ≤1) and slight pollution (1 < NPI ≤2) in Big Giftun. Cd showed moderate potential ecological risk (40 ≤ Eri < 80) in Big Giftun sediments. Potential ecological risk index (PERI) indicated low risk sediments (PERI <150). Mean effects range median quotient (MERMQ) indicated low-priority risk of toxicity (MERMQ ≤0.1), and toxic risk index (TRI) showed no toxic risk in all sediments (TRI <5). The modified hazard quotient (mHQ) indicated very low severity of contamination (mHQ <0.5). The hazard quotient (HQ) levels of all metals were below the safe value (HQ <1). The hazard index (HI) levels indicated that no chronic risks occur (HI <1). The total cancer risk (TCR) for all metals were below the safe level (1 × 10-4) of the United States Environmental Protection Agency (U.S. EPA) guidelines.


Assuntos
Metais Pesados , Poluentes Químicos da Água , Oceano Índico , Cádmio , Egito , Sedimentos Geológicos , Medição de Risco , Monitoramento Ambiental , Poluentes Químicos da Água/análise , Metais Pesados/análise , Manganês , Zinco , Cobalto , Níquel
2.
Mar Pollut Bull ; 194(Pt B): 115367, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37567130

RESUMO

The objective of this study is to assess the natural resources and radiological risks of Wadi El Gemal Island by examining its topography, mineralogy, geochemistry, and radioactive distributions. This island, which is situated at the outlet of Wadi El Gemal in Egypt's southeastern Desert, has a unique shape resembling a dolphin based on Landsat imagery. It's a part of the Wadi El Gemal-Hamata Protectorate and is notable for its diverse environmental, geological, economic, and archeological features, including recent reefs, sandy deposits, Quaternary carbonate sediments, and mangroves. The main natural resources on the island are fauna, mangrove forests, and flora. Samples collected from the island were analyzed using a NaI detector to measure the concentrations of radionuclides such as 238U, 232Th, 226Ra, and 40K, which were found to be within acceptable levels according to UNSCAR guidelines. The radionuclide 238U, 232Th, 226Ra, and 40K activity concentrations of the collected samples were 32.55 ± 9, 12.63 ± 4, 12.49 ± 4, and 325 ± 34 Bq/kg, respectively. Regarding radiological hazard indices, the values of absorbed gamma dose rate (36.06 ± 5.42 nGy/h), radium equivalent activity (73.88 ± 14.4 Bq/kg), annual effective dose indoor (0.18 ± 0.03 mSv/y) and outdoor (0.04 ± 0.01 mSv/y), internal (0.29 ± 0.05) and external (0.2 ± 0.03) indices, and excess lifetime cancer index (0.15 ± 0.05 × 10-3).This is suggest that there is no significant risk associated with these sediments.


Assuntos
Monitoramento de Radiação , Radioatividade , Rádio (Elemento) , Poluentes Radioativos do Solo , Radioisótopos/análise , Rádio (Elemento)/análise , Recursos Naturais , Tório/análise , Poluentes Radioativos do Solo/análise , Radioisótopos de Potássio/análise , Espectrometria gama
3.
Sci Rep ; 13(1): 11497, 2023 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-37460601

RESUMO

Emerald and other beryls represent a family of the most valuable gemstone around the world and particularly in Egypt. Beryllium (Be) contents in beryl-bearing bedrocks in south Sinai (Wadi Ghazala and Wadi Sedri), and in central and south Eastern Desert of Egypt (Igla area, Zabara-Um Addebaa belt, Homret Akarem, and Homret Mukpid) were investigated in this study. The environmental risk levels of Be, associated major ions, and heavy metals in groundwater nearby to beryl-bearing mineralization were also evaluated. Results showed that Be contents ranged from 1 to 374 ppm in beryl-bearing bedrocks, while in nearby groundwater, Be content has a range of 0.0001-0.00044 mg/L with an average of 0.00032 mg/L, which is within the permissible levels and below (0.004) the U.S. EPA maximum contaminant level (MCL). Most levels of heavy metals (e.g., Be, B, Ni, V, Fe, and Al) in the investigated groundwater of central and south Eastern Desert and south Sinai are within the permissible levels and below their corresponding U.S. EPA MCLs. This study also investigated the radiological risk of natural radionuclides distributed in beryl-bearing bedrocks in the study area using gamma spectrometry; Sodium Iodide [NaI(Tl)] scintillation detector. Among the estimated mean 238U, 232Th, and 226Ra activity concentrations of the studied beryl-bearing rocks, Homret Mukpid (79, 87.15, 60.26 Bq kg-1) and Homret Akarem (111.6, 51.17, 85.1 Bq kg-1) contain the highest values. This may be attributed to their highly fractionated granitic rocks that host uranium and thorium reservoir minerals such as zircon, allanite, and monazite. The estimated data of multi-radiological parameters such as absorbed gamma dose, outdoor and indoor annual effective dose, radium equivalent activity, internal and external indices, index of excess cancer, and effective dose to human organs reflecting no significant impacts from the emitted natural gamma radiation.

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